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http://hdl.handle.net/20.500.12128/10377
Tytuł: | Non-K Region Disubstituted Pyrenes (1,3-, 1,6- and 1,8-) by (Hetero)Aryl Groups - Review |
Autor: | Zych, Dawid |
Słowa kluczowe: | pyrene chemistry; synthetic methods; substitution pattern; bromination; acylation; coupling reactions; condensation; cycloaddition |
Data wydania: | 2019 |
Źródło: | Molecules, Vol 24 (2019), Art. No. 2551 |
Abstrakt: | Disubstituted pyrenes at the non-K region by the same or di erent (hetero)aryl groups
have proven to be an increasingly interesting area of research for scientists over the last decade due to
their optical and photophysical properties. However, in this area, there is no systematization of the
structures and synthesis methods nor their limitations. In this review, all approaches to the synthesis
of these compounds, starting from the commercially available pyrene are described. Herein, the ways
of obtaining of disubstituted intermediates based on bromination and acylation reaction are presented.
This is crucial in the determination of the possibility of further functionalization by using coupling,
cycloaddition, condensation, etc. reactions. Moreover, the application of disubstituted pyrenes in
the synthesis of 1,3,6,8-tetrasubstituted was also reviewed. This review describes the directions of
research on chemistry of disubstituted pyrenes. |
URI: | http://hdl.handle.net/20.500.12128/10377 |
DOI: | 10.3390/molecules24142551 |
ISSN: | 1420-3049 |
Pojawia się w kolekcji: | Artykuły (WNŚiT)
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