DC pole | Wartość | Język |
dc.contributor.author | Kupczak, Krzysztof | - |
dc.contributor.author | Warchulski, Rafał | - |
dc.contributor.author | Dulski, Mateusz | - |
dc.contributor.author | Środek, Dorota | - |
dc.date.accessioned | 2020-11-16T10:37:41Z | - |
dc.date.available | 2020-11-16T10:37:41Z | - |
dc.date.issued | 2020 | - |
dc.identifier.citation | "Minerals" (2020), vol. 10, iss. 11, art. no. 1006, s. 1-19 | pl_PL |
dc.identifier.issn | 2075-163X | - |
dc.identifier.uri | http://hdl.handle.net/20.500.12128/17069 | - |
dc.description.abstract | Slags from the historic metallurgy of Zn-Pb ores are known for unique chemical and phase
compositions. The oxides, silicates, aluminosilicates, and amorphous phases present therein often
contain in the structure elements that are rare in natural conditions, such as Zn, Pb, As. The study
focuses on processes occurring on the contact of the melted batch and the refractory materials that
build the furnace, which lead to the formation of these phases. To describe them, chemical (X-ray
fluorescence (XRF), inductively coupled plasma mass spectrometry (ICP-MS)) and petrological
((X-ray di raction (XRD), electron probe micro-analyses (EPMA), Raman spectroscopy) analyses
were performed on refractory material, slag, and contact of both. Two main types of reactions have
been distinguished: gas/fluid- refractories and liquid- refractories. The first of them enrich the
refractories with elements that migrate with the gas (Pb, K, Na, As, Zn) and transport the components
building it (Fe, Mg, Ca) inward. Reactions between melted batch and refractory materials through
gravitational di erentiation and the melting of refractories lead to the formation of an aluminosilicate
liquid with a high content of heavy elements. Cooling of this melt causes crystallization of minerals
characteristic for slag, but with a modified composition, such as Fe-rich pyroxenes, Pb-rich K-feldspar,
or PbO-As2O3-SiO2 glass. | pl_PL |
dc.language.iso | en | pl_PL |
dc.rights | Uznanie autorstwa 3.0 Polska | * |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/pl/ | * |
dc.subject | slags | pl_PL |
dc.subject | refractory material | pl_PL |
dc.subject | zinc | pl_PL |
dc.subject | lead | pl_PL |
dc.subject | smelting | pl_PL |
dc.subject | metallurgy | pl_PL |
dc.title | Chemical and Phase Reactions on the Contact between Refractory Materials and Slags, a Case from the 19th Century Zn-Pb Smelter in Ruda S´ la˛ska, Poland | pl_PL |
dc.type | info:eu-repo/semantics/article | pl_PL |
dc.identifier.doi | 10.3390/min10111006 | - |
Pojawia się w kolekcji: | Artykuły (WNP)
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