DC pole | Wartość | Język |
dc.contributor.author | Grobelny, Zbigniew | - |
dc.contributor.author | Jurek-Suliga, Justyna | - |
dc.contributor.author | Golba, Sylwia | - |
dc.date.accessioned | 2020-12-21T08:06:27Z | - |
dc.date.available | 2020-12-21T08:06:27Z | - |
dc.date.issued | 2020 | - |
dc.identifier.citation | Polymer Bulletin (2020) (online first) | pl_PL |
dc.identifier.issn | 0170-0839 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.12128/17899 | - |
dc.description.abstract | Cesium hydroxide monohydrate (CsOH·H2O) activated by cation complexing agents, i.e., 18C6 or C222 was applied as initiator of monosubstituted oxiranes polymerization. Propylene oxide (PO), 1,2-butylene oxide (BO), styrene oxide (SO) and some glycidyl ethers were used as monomers. All processes were carried out in tetrahydrofuran solution at room temperature. Such polymers, as PPO-diols, PBO-diols and PSO-diols, are unimodal and have molar masses Mn = 2000-5100. Their dispersities are rather high (Mw/Mn = 1.17-1.33). Moreover, PPO-diols and PSO-diols are not contaminated by monools with unsaturated starting groups. Poly(glycidyl ether)s are, in general, polymodal. For example, poly(isopropyl glycidyl ether)-diols are bi- or trimodal, whereas poly(allyl glycidyl ether)-diols possess two or even six fractions. Molar masses of main fraction are 4200-6400, and the second fraction is much lower, namely 600-2600. Dispersities of some fractions are very low (Mw/Mn = 1.01-1.07). Polymodality of polymers obtained was discussed in terms of the formation of two or more species propagating with different rate constants. | pl_PL |
dc.language.iso | en | pl_PL |
dc.rights | Uznanie autorstwa 3.0 Polska | * |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/pl/ | * |
dc.subject | cesium hydroxide monohydrate | pl_PL |
dc.subject | ring opening polymerization | pl_PL |
dc.subject | monosubstituted oxiranes | pl_PL |
dc.subject | polyether-diol | pl_PL |
dc.title | Application of cesium hydroxide monohydrate for ring opening polymerization of monosubstituted oxiranes : characterization of synthesized polyether-diols | pl_PL |
dc.type | info:eu-repo/semantics/article | pl_PL |
dc.relation.journal | Polymer Bulletin | pl_PL |
dc.identifier.doi | 10.1007/s00289-020-03480-1 | - |
Pojawia się w kolekcji: | Artykuły (WNŚiT)
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