DC pole | Wartość | Język |
dc.contributor.author | Sawicki, Bogdan | - |
dc.contributor.author | Tomaszewicz, E. | - |
dc.contributor.author | Groń, Tadeusz | - |
dc.contributor.author | Berkowski, M. | - |
dc.contributor.author | Głowacki, M. | - |
dc.contributor.author | Oboz, Monika | - |
dc.contributor.author | Kusz, Joachim | - |
dc.contributor.author | Pawlus, Sebastian | - |
dc.date.accessioned | 2021-04-20T07:07:51Z | - |
dc.date.available | 2021-04-20T07:07:51Z | - |
dc.date.issued | 2020 | - |
dc.identifier.citation | Journal of Materiomics, (2020) | pl_PL |
dc.identifier.issn | 2352-8478 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.12128/20012 | - |
dc.description.abstract | Single crystal of Eu3+-doped cadmium molybdate (Cd0.9268 M 0.0244Eu0.0488MoO4, where M denotes
cationic vacancies) has been successfully grown by the Czochralski method in air and under 1 MPa. X-ray
diffraction analysis indicates that as-grown single crystal exhibits tetragonal scheelite-type structure
(a = b = 5.16188(14) A; c = 11.2080(5) A; space group I41/a). Eu3+ ions do not show long-range order and
they are randomly distributed in CdMoO4 framework substituting Cd2+ ones. UVevis diffuse reflectance
measurements revealed very close optical band gap (Eg) values, i.e. ~1.74 eV along [100] and [001]
crystallographic directions that are twice smaller than Eg of microcrystalline pure CdMoO4 as well as
powder Eu3+-doped single crystal. Magnetic and electrical studies of Eu3+-doped cadmium molybdate
single crystal showed a paramagnetic and n-type semiconducting behaviour with the metal-insulator
transition above 350 K along both crystallographic directions. Dielectric results analysis using the
Cole-Cole fit function revealed that the dipole relaxation process has different time scale depending on
the crystallographic direction and exhibits Arrhenius temperature dependence for both studied directions.
This fact is accompanied by the colossal dielectric permittivity with er > 8 • 103. The above results
are considered in the framework of narrow europium multiplets of energy comparable to thermal energy. | pl_PL |
dc.language.iso | en | pl_PL |
dc.rights | Uznanie autorstwa-Użycie niekomercyjne-Bez utworów zależnych 3.0 Polska | * |
dc.rights | Uznanie autorstwa-Użycie niekomercyjne-Bez utworów zależnych 3.0 Polska | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/pl/ | * |
dc.subject | Scheelite | pl_PL |
dc.subject | Single crystal | pl_PL |
dc.subject | Solid solution | pl_PL |
dc.subject | Paramagnetic behaviour | pl_PL |
dc.subject | Relaxation process | pl_PL |
dc.subject | Giant dielectric permittivity | pl_PL |
dc.title | Dipole relaxation process and giant dielectric permittivity in Eu3+- doped CdMoO4 single crystal | pl_PL |
dc.type | info:eu-repo/semantics/article | pl_PL |
dc.identifier.doi | 10.1016/j.jmat.2020.12.010 | - |
Pojawia się w kolekcji: | Artykuły (WNŚiT)
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