Heavy metal accumulation in two peat bogs from Southern Poland

Abstract

The dynamic changes in selected heavy metal concentrations were analyzed in two ombrotrophic peat bogs from southern Poland: Puścizna Mała (PK) and Puścizna Krauszowska (PM). The highest contents of Pb and Zn occur at the top of profiles examined: 115.36 mg/kg (PM1), 90.61 mg/kg (PM2), 182.40 mg/kg (PK1), 121.68 mg/kg (PK2) and 127.43 mg/kg (PM1), 89.73 mg/kg (PM2), 170 mg/kg (PK1), 130.4 mg/kg (PK2), respectively. Concentrations of copper are similar to those of local soils varying from 9.4 to 12.8 mg/kg. Cadmium strongly varies with depth, which indicates distinct mobility of this element. Two peaks of elevated Fe concentrations are observed at the top and bottom of the Puścizna Mała profile, while the maximum in Puścizna Krauszowska was at the top of the peat bog. The Ti content distinctly varies with depth and correlates with the ash content (R2 = 0.91-0.99). The strongest and positive correlation is observed between Zn-Pb and Ti-Pb contents. The significant differences of metal concentrations are noted between the profiles, which is probably connected with a rate of peat accumulation and plant composition of the profiles investigated, as well as with their disturbance by human activity.