DC pole | Wartość | Język |
dc.contributor.author | Różkowski, Jacek | - |
dc.contributor.author | Różkowski, Kazimierz | - |
dc.contributor.author | Rahmonov, Oimahmad | - |
dc.contributor.author | Rubin, Hanna | - |
dc.date.accessioned | 2019-04-04T06:27:22Z | - |
dc.date.available | 2019-04-04T06:27:22Z | - |
dc.date.issued | 2017 | - |
dc.identifier.citation | Environmental Science And Pollution Research International, Vol. 24, iss. 33 (2017), s. 25870-25880 | pl_PL |
dc.identifier.issn | 1614-7499 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.12128/8727 | - |
dc.description.abstract | The paper presents the varied presence of nitrates
and phosphates in water from caves located in Częstochowa
and Kraków, in urban, strongly anthropogenic conditions,
representing the vadose zone of the fissure-karstic-porous massif
of Upper Jurassic limestones. Hydrochemical research was
carried out by the authors in the Cave on the Stone in
Częstochowa in 2012–2015, in caves of the Zakrzówek horst
from 1996 to 2002, and in the Dragon’s Cave by the research
team of J. Motyka in 1995–1998. A number of NO3 and PO4
measurements were performed in waters sampled at these research
sites: 20 measurements each ofNO3 and PO4 at the Cave
on the Stone, 228 of NO3 and 422 of PO4 at Zakrzówek, and 19
each of NO3 and PO4 at the Dragon’s Cave. To assess the
quality aspect of N and P compounds in waters from the
Cave on the Stone, the results of geochemical modelling were
processed using PHREEQC software. In cave waters, the
oxidised form of nitrogen NO3
− predominates; in surface waters
in the vicinity, unoxidised forms prevail: NH4+, NH3, and
NH4SO4
−. Among phosphorus speciations, dissolved forms are
dominant: HPO4
2−, H2PO4
−, and the insoluble form CaHPO4;
in surface waters, these forms are practically absent.
Transformations of water chemistry in ‘urban’ caves, often
centuries old, manifest themselves in, inter alia, the occurrence
of multi-ionic waters, including seasonal variations and extremely
diversified concentrations, with very high concentrations
in subpopulations of NO3 (0.2–485 mg dm−3) and P
(0.02–6.87 mg dm−3). The common presence of NO3 in waters
of the phreatic zone of the Częstochowa Upland, an area developed
in an agricultural direction, is documented by, inter
alia, the exploitation of intakes supplying the city of
Częstochowa (10–57 mg dm−3, 2011) and crenological studies
from 2008 to 2015 (NO3, 2–58 mg dm−3), at simultaneously
low phosphate concentrations (PO4, 0.02–0.24 mg dm−3). | pl_PL |
dc.language.iso | en | pl_PL |
dc.rights | Uznanie autorstwa 3.0 Polska | * |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/pl/ | * |
dc.subject | Water pollution | pl_PL |
dc.subject | Nitrates and phosphates | pl_PL |
dc.subject | Cave wate | pl_PL |
dc.subject | Kraków-Częstochowa upland | pl_PL |
dc.subject | Poland | pl_PL |
dc.title | Nitrates and phosphates in cave waters of Kraków-Częstochowa Upland, southern Poland | pl_PL |
dc.type | info:eu-repo/semantics/article | pl_PL |
dc.relation.journal | Environmental Science And Pollution Research International | pl_PL |
dc.identifier.doi | 10.1007/s11356-017-0215-8 | - |
Pojawia się w kolekcji: | Artykuły (WNP)
|