DC pole | Wartość | Język |
dc.contributor.author | Rodriguez-Tinoco, Cristian | - |
dc.contributor.author | Rams-Baron, Marzena | - |
dc.contributor.author | Ngai, K. L. | - |
dc.contributor.author | Jurkiewicz, Karolina | - |
dc.contributor.author | Rodriguez-Viejoc, Javier | - |
dc.contributor.author | Paluch, Marian | - |
dc.date.accessioned | 2019-04-15T08:37:45Z | - |
dc.date.available | 2019-04-15T08:37:45Z | - |
dc.date.issued | 2018 | - |
dc.identifier.citation | Physical Chemistry Chemical Physics, 2018, iss. 6, s. 3939-3945 | pl_PL |
dc.identifier.issn | 1463-9076 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.12128/8832 | - |
dc.description.abstract | Secondary relaxations are fundamental for their impact in the properties of glasses and for their
inseparable connection to the structural relaxation. Understanding their density dependence and aging
behavior is key to fully address the nature of glasses. Ultrastable glasses establish a new benchmark to
study the characteristics of secondary relaxations, since their enthalpy and density levels are unattainable
by other routes. Here, we use dielectric spectroscopy at ambient and elevated pressures to study the
characteristics of the secondary relaxation in ultrastable etoricoxib, reporting a 71% decrease in dielectric
strength and one decade increase in relaxation time compared to the ordinary glass. Interestingly, we
find an unprecedented connection between secondary and structural relaxations in ultrastable etoricoxib
in exactly the same manner as in the ordinary glass, manifested through different properties, such as
aging and devitrification. These results further support and extend the general validity of the connection
between the secondary and structural relaxation. | pl_PL |
dc.language.iso | en | pl_PL |
dc.rights | Uznanie autorstwa 3.0 Polska | * |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/pl/ | * |
dc.subject | glass | pl_PL |
dc.subject | stable glasses | pl_PL |
dc.subject | Vapor deposition | pl_PL |
dc.title | Secondary relaxation in ultrastable etoricoxib : evidence of correlation with structural relaxation | pl_PL |
dc.type | info:eu-repo/semantics/article | pl_PL |
dc.relation.journal | Physical Chemistry Chemical Physics | pl_PL |
dc.identifier.doi | 10.1039/c7cp06445d | - |
Pojawia się w kolekcji: | Artykuły (WNŚiT)
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