http://hdl.handle.net/20.500.12128/9329
Title: | Chloride and pseudohalide hydride-carbonyl ruthenium(II) complexes with 4-pyrrolidinopyridine as co-ligand |
Authors: | Małecki, Jan Grzegorz Maroń, Anna |
Keywords: | ruthenium; X ray crystallography |
Issue Date: | 2013 |
Citation: | Transition Metal Chemistry, 2013, iss. 2, s. 133-142 |
Abstract: | Chloride and pseudohalide (N3 -, NCS-) hydride-carbonyl ruthenium(II) complexes with 4-pyrrolidinopyridine as co-ligand were synthesized and characterized by IR, 1H, and 31P NMR, electronic absorption and emission spectroscopy and X-ray crystallography. The electronic structures of the complexes were calculated by density functional theory (DFT) on their crystal structures. The spin-allowed singlet–singlet electronic transitions of the complexes were calculated by time-dependent DFT, and the UV–Vis spectra have been discussed on these basis. The emission properties of the complexes were also studied. |
URI: | http://hdl.handle.net/20.500.12128/9329 |
DOI: | 10.1007/s11243-012-9670-8 |
ISSN: | 0340-4285 |
Appears in Collections: | Artykuły (WNŚiT) |
File | Description | Size | Format | |
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Malecki_Chloride_and_pseudohalide_hydride_carbonyl.pdf | 591,29 kB | Adobe PDF | View/Open |
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