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Title: A ruthenium(II) hydride carbonyl complex with 4-phenylpyrimidine as co-ligand
Authors: Małecki, Jan Grzegorz
Maron, A.
Keywords: ruthenium; X ray crystallography
Issue Date: 2012
Citation: Transition Metal Chemistry, 2012, iss. 8, s. 727-734
Abstract: The reaction of [RuHCl(CO)(PPh3)3] with 4-phenylpyrimidine gave a new ruthenium(II) complex, namely [RuHCl(CO)(PPh3)2(pyrim-4-Ph)]. The complex has been studied by IR and UV–vis spectroscopy and by X-ray crystallography. The molecular orbitals of the complex have been calculated by density functional theory. The spin-allowed singlet–singlet electronic transitions of the complex have been calculated by time-dependent DFT, and the UV–vis spectrum of the compound has been discussed on this basis. The emission properties of the complex were also studied.
DOI: 10.1007/s11243-012-9644-x
ISSN: 0340-4285
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