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Title: Influence of the substituent D/A at the 1,2,3-triazole ring on novel terpyridine derivatives:synthesis and properties
Authors: Zych, Dawid
Słodek, Aneta
Zimny, Dżastin
Golba, Sylwia
Malarz, Katarzyna
Mrozek-Wilczkiewicz, Anna
Keywords: Substitution reactions; 1 ,3-Dipolarcycloaddition
Issue Date: 2019
Citation: RSC Advances, Vol. 9 (2019), s. 16554-16564
Abstract: In this study, we newly designed and developed a synthesis route based on the 1,3-dipolar cycloaddition of the derivatives of 40-(1,2,3-triazol-4-yl)phenyl-2,20:60,200-terpyridine with various (hetero)aryl substituents, differing in electronic character, on a triazol ring. The obtained compounds were comprehensively characterized by UV-Vis spectroscopy and electrochemical and thermal studies. Moreover, preliminary biological tests were conducted. The investigation allowed the selection of materials with the most promising properties with particular emphasis on the nature of the substituents. In addition, theoretical studies (DFT and TD-DFT) were performed to verify the comprehensive understanding of experimental results.
DOI: 10.1039/c9ra02655j
ISSN: 2046-2069
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