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Tytuł: Organonickel complexes encumbering bis-imidazolylidene carbene ligands: Synthesis, X-ray structure and catalytic insights on Buchwald- Hartwig amination reactions
Autor: Nirmala, Muthukumaran
Saranya, Gandh
Viswanathamurthi, Periasamy
Bertani, Roberta
Sgarbossa, Paolo
Małecki, Jan Grzegorz
Słowa kluczowe: Diimidazolium NHC ligand; NieNHC complexes; X-ray diffraction; CeN coupling reaction
Data wydania: 2017
Wydawca: Elsevier
Źródło: Journal of Organometallic Chemistry, Vol. 831 (2017), s. 1-10
Abstrakt: New four coordinated homoleptic bis(diimidazolylidene)nickel(II) complexes (C1 & C2) were synthesized and characterized by elemental analysis, NMR (1H and 13C) as well as ESI-Mass spectrometry. The molecular structure of the complex C1 was identified by means of single-crystal X-ray diffraction analysis, which revealed that the complexes possess a distorted square planar geometry with chelating bis(diimidazolylidene) NHC ligands and two non coordinating bromide counter ions in tetradentate C4 fashion. A survey of their catalytic activity in Buchwald Hartwig amination has been performed. The newly synthesized complexes also catalyzed the amination of aryl chlorides in the presence of KOtBu. Various aryl chlorides and amines can react smoothly to give the corresponding aminated products in moderate to high yields. The scope of the reaction encompasses electronically varied aryl chlorides and nitrogen-containing heteroaryl chlorides, including pyridine and quinoline derivatives. Both secondary and primary amines are well tolerated under the optimal reaction conditions.
DOI: 10.1016/j.jorganchem.2016.12.029
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