DC pole | Wartość | Język |
dc.contributor.author | Peppel, Tim | - |
dc.contributor.author | Geppert-Rybczyńska, Monika | - |
dc.contributor.author | Neise, Christin | - |
dc.contributor.author | Kragl, Udo | - |
dc.contributor.author | Köckerling, Martin | - |
dc.date.accessioned | 2020-01-14T20:56:56Z | - |
dc.date.available | 2020-01-14T20:56:56Z | - |
dc.date.issued | 2019 | - |
dc.identifier.citation | "Materials" iss. 22 (2019), art. no. 3764 | pl_PL |
dc.identifier.issn | 1996-1944 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.12128/12030 | - |
dc.description.abstract | The synthesis of more than 10 new magnetic ionic liquids with [MnX4]2 anions, X = Cl,
NCS, NCO, is presented. Detailed structural information through single-crystal X-ray di raction
is given for (DMDIm)[Mn(NCS)4], (BnEt3N)2[Mn(NCS)4], and {(Ph3P)2N}2[Mn(NCO4)] 0.6H2O,
respectively. All compounds consist of discrete anions and cations with tetrahedrally coordinated
Mn(II) atoms. They show paramagnetic behavior as expected for spin-only systems. Melting points
are found for several systems below 100 C classifying them as ionic liquids. Thermal properties
are investigated using di erential scanning calorimetry (DSC) measurements. The physicochemical
properties of density, dynamic viscosity, electrolytic conductivity, and surface tension were measured
temperature-dependent of selected samples. These properties are discussed in comparison to similar
Co containing systems. An increasing amount of bromide impurity is found to a ect the surface
tension only up to 3.3%. | pl_PL |
dc.language.iso | en | pl_PL |
dc.rights | Uznanie autorstwa 3.0 Polska | * |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/pl/ | * |
dc.subject | manganese | pl_PL |
dc.subject | ionic liquid | pl_PL |
dc.subject | crystal structure | pl_PL |
dc.subject | physical properties | pl_PL |
dc.subject | trace impurities | pl_PL |
dc.title | Low-melting manganese(II)-based ionic liquids: syntheses, structures, properties and influence of trace impurities | pl_PL |
dc.type | info:eu-repo/semantics/article | pl_PL |
dc.identifier.doi | 10.3390/ma12223764 | - |
Pojawia się w kolekcji: | Artykuły (WNŚiT)
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