DC pole | Wartość | Język |
dc.contributor.author | Nawrot, Iwona | - |
dc.contributor.author | Machura, Barbara | - |
dc.contributor.author | Kruszyński, R. | - |
dc.date.accessioned | 2020-02-17T14:19:44Z | - |
dc.date.available | 2020-02-17T14:19:44Z | - |
dc.date.issued | 2016 | - |
dc.identifier.citation | "CrystEngComm" Vol. 18 (2016), s. 2650-2663 | pl_PL |
dc.identifier.issn | 1466-8033 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.12128/12657 | - |
dc.description.abstract | A systematic investigation of CdIJII)–(py)2CO–X systems (X = N3 −, NCO− and NCS−) was conducted, and the
following cadmium(II) coordination compounds [Cd(SCN)2{(py)2C(OCH3)(OH)}]n (1), [Cd2(SCN)4{(py)2-
C(OCH3)(OH)}2] (2), [Cd4(SCN)4{(py)2C(OCH3)(O)}4] (3), [Cd4(N3)4{(py)2C(OCH3)(O)}4] (4), [Cd4(N3)4{(py)2-
C(OH)(O)}2{(py)2C(OCH3)(O)}2] (5), [Cd4(NCO)4{(py)2C(OCH3)(O)}4] (6), [Cd4(NCO)4{(py)2C(OH)(O)}2{(py)2-
C(OCH3)(O)}2] (7), [Cd4(N3)2(NO3)2{(py)2C(OH)(O)}2{(py)2C(OCH3)(O)}2] (8) and
[Cd4(NCO)2(NO3)2{(py)2C(OH)(O)}2{(py)2C(OCH3)(O)}2] (9a and 9b) were successfully synthesized and characterized by single-crystal diffraction, X-ray powder diffraction (XRPD), differential scanning calorimetry
(DSC) analysis and IR spectroscopy. The fluorescence properties of 1–9 were studied in the solid state and
compared to the fluorescence of di-2-pyridyl ketone. The photoluminescence behaviour of 2–9 was also
investigated in acetonitrile solution. The X-ray studies demonstrated a cooperative impact of the organic ligand
and auxiliary inorganic ion on the final molecular architectures of the cadmium(II) coordination compounds.
Also, the essential roles of intermolecular interactions (hydrogen bonds, π–π stacking interactions
and weak O⋯S contacts) in the creation of molecular architectures were discussed. | pl_PL |
dc.language.iso | en | pl_PL |
dc.rights | Uznanie autorstwa-Użycie niekomercyjne 3.0 Polska | * |
dc.rights | Uznanie autorstwa-Użycie niekomercyjne 3.0 Polska | * |
dc.rights | Uznanie autorstwa-Użycie niekomercyjne 3.0 Polska | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc/3.0/pl/ | * |
dc.subject | X-ray powder diffraction (XRPD), | pl_PL |
dc.subject | differential scanning calorimetry(DSC) | pl_PL |
dc.title | Exploration of Cd(II)/pseudohalide/di-2-pyridyl ketone chemistry - rational synthesis, structural analysis and photoluminescence | pl_PL |
dc.type | info:eu-repo/semantics/article | pl_PL |
dc.identifier.doi | 10.1039/c6ce00112b | - |
Pojawia się w kolekcji: | Artykuły (WNŚiT)
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