DC pole | Wartość | Język |
dc.contributor.author | Szłapa-Kula, Agata | - |
dc.contributor.author | Małecka, Magdalena | - |
dc.contributor.author | Maroń, Anna M. | - |
dc.contributor.author | Janeczek, Henryk | - |
dc.contributor.author | Siwy, Mariola | - |
dc.contributor.author | Schab-Balcerzak, Ewa | - |
dc.contributor.author | Szalkowski, Marcin | - |
dc.contributor.author | Maćkowski, Sebastian | - |
dc.contributor.author | Pedzinski, Tomasz | - |
dc.contributor.author | Erfurt, Karol | - |
dc.contributor.author | Machura, Barbara | - |
dc.date.accessioned | 2021-12-21T10:23:32Z | - |
dc.date.available | 2021-12-21T10:23:32Z | - |
dc.date.issued | 2021 | - |
dc.identifier.citation | "Inorganic Chemistry" (2021), iss, 24, s. 18726-18738 | pl_PL |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.12128/22161 | - |
dc.description.abstract | In the current work, comprehensive photophysical and electrochemical
studies were performed for eight rhenium(I) complexes incorporating
2,2′:6′,2″-terpyridine (terpy) and 2,6-bis(pyrazin-2-yl)pyridine (dppy) with
appended 1-naphthyl-, 2-naphthyl-, 9-phenanthrenyl, and 1-pyrenyl groups.
Naphthyl and phenanthrenyl substituents marginally affected the energy of the
MLCT absorption and emission bands, signaling a weak electronic coupling of
the appended aryl group with the Re(I) center. The triplet MLCT state in these
complexes is so low lying relative to the triplet 3ILaryl that the thermal population
of the triplet excited state delocalized on the organic chromophore is ineffective.
The attachment of the electron-rich pyrenyl group resulted in a noticeable red
shift and a significant increase in molar absorption coefficients of the lowest
energy absorption of the resulting Re(I) complexes due to the contribution of
intraligand charge-transfer (ILCT) transitions occurring from the pyrenyl
substituent to the terpy/dppy core. At 77 K, the excited states of [ReCl(CO)3(Ln-κ2N)] with 1-pyrenyl-functionalized ligands
were found to have predominant 3ILpyrene/3ILCTpyrene→terpy character. The 3IL/3ILCT nature of the lowest energy excited state of
[ReCl(CO)3(4′-(1-pyrenyl)-terpy-κ2N)] was also evidenced by nanosecond transient absorption and time-resolved emission
spectroscopy. Enhanced room-temperature emission lifetimes of the complexes [ReCl(CO)3(Ln-κ2N)] with 1-pyrenyl-substituted
ligands are indicative of the thermal activation between 3MLCT and 3IL/3ILCT excited states. Deactivation pathways occurring
upon light excitation in [ReCl(CO)3(4′-(1-naphthyl)-terpy-κ2N)] and [ReCl(CO)3(4′-(1-pyrenyl)-terpy-κ2N)] were determined by
femtosecond transient absorption studies. | pl_PL |
dc.language.iso | en | pl_PL |
dc.rights | Uznanie autorstwa 3.0 Polska | * |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/pl/ | * |
dc.subject | Metal to ligand charge transfer | pl_PL |
dc.subject | Absorption | pl_PL |
dc.subject | Ligands | pl_PL |
dc.subject | Energy | pl_PL |
dc.subject | Quantum mechanichs | pl_PL |
dc.title | In-depth studies of ground- and excited-state properties of Re(I) carbonyl complexes bearing 2,2′:6′,2′′-terpyridine and 2,6-bis(pyrazin-2-yl)pyridine coupled with π‑conjugated aryl chromophores | pl_PL |
dc.type | info:eu-repo/semantics/article | pl_PL |
dc.identifier.doi | 10.1021/acs.inorgchem.1c02151 | - |
Pojawia się w kolekcji: | Artykuły (WNŚiT)
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