DC pole | Wartość | Język |
dc.contributor.author | Krompiec, Stanisław | - |
dc.contributor.author | Kurpanik-Wójcik, Aneta | - |
dc.contributor.author | Matussek, Marek | - |
dc.contributor.author | Gołęk, Bogumiła | - |
dc.contributor.author | Mieszczanin, Angelika | - |
dc.contributor.author | Fijołek, Aleksandra | - |
dc.date.accessioned | 2022-01-03T11:40:01Z | - |
dc.date.available | 2022-01-03T11:40:01Z | - |
dc.date.issued | 2022 | - |
dc.identifier.citation | "Materials" (2022), iss. 1, art. no 172, s. 1-149 | pl_PL |
dc.identifier.issn | 1996-1944 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.12128/22200 | - |
dc.description.abstract | Phenyl, naphthyl, polyarylphenyl, coronene, and other aromatic and polyaromatic moieties
primarily influence the final materials’ properties. One of the synthetic tools used to implement (hetero)
aromatic moieties into final structures is Diels–Alder cycloaddition (DAC), typically combined
with Scholl dehydrocondensation. Substituted 2-pyranones, 1,1-dioxothiophenes, and, especially,
1,3-cyclopentadienones are valuable substrates for [4 + 2] cycloaddition, leading to multisubstituted
derivatives of benzene, naphthalene, and other aromatics. Cycloadditions of dienes can be carried
out with extrusion of carbon dioxide, carbon oxide, or sulphur dioxide. When pyranones, dioxothiophenes,
or cyclopentadienones and DA cycloaddition are aided with acetylenes including masked
ones, conjugated or isolated diynes, or polyynes and arynes, aromatic systems are obtained. This
review covers the development and the current state of knowledge regarding thermal DA cycloaddition
of dienes mentioned above and dienophiles leading to (hetero)aromatics via CO, CO2, or
SO2 extrusion. Particular attention was paid to the role that introduced aromatic moieties play in
designing molecular structures with expected properties. Undoubtedly, the DAC variants described
in this review, combined with other modern synthetic tools, constitute a convenient and efficient way
of obtaining functionalized nanomaterials, continually showing the potential to impact materials
sciences and new technologies in the nearest future. | pl_PL |
dc.language.iso | en | pl_PL |
dc.rights | Uznanie autorstwa 3.0 Polska | * |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/pl/ | * |
dc.subject | Diels–Alder cycloaddition | pl_PL |
dc.subject | extrusion | pl_PL |
dc.subject | APEX strategy | pl_PL |
dc.subject | functionalized nanomaterials | pl_PL |
dc.subject | nanographenes | pl_PL |
dc.subject | organic electronics | pl_PL |
dc.subject | polycyclic aromatic hydrocarbons | pl_PL |
dc.subject | polyarenes | pl_PL |
dc.title | Diels-Alder cycloaddition with CO, CO2, SO2, or N2 extrusion : a powerful tool for material chemistry | pl_PL |
dc.type | info:eu-repo/semantics/article | pl_PL |
dc.identifier.doi | 10.3390/ma15010172 | - |
Pojawia się w kolekcji: | Artykuły (WNŚiT)
|