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Zastosuj identyfikator do podlinkowania lub zacytowania tej pozycji: http://hdl.handle.net/20.500.12128/22717
Tytuł: Synthesis and Photoluminescence Properties of Pr3+-Doped Ba0.5Ca0.5TixZr(1-x)O3 Perovskite Diphasic Ceramics Obtained by the Modified Pechini Method
Autor: Wilk, Agnieszka
Kozielski, Lucjan
Michalik, Daniel
Kozień, Dawid
Makowska, Jolanta
Pędzich, Zbigniew
Słowa kluczowe: photoluminescence; perovskite crystal structure; rare-earth-element doping; carrier trap; dielectric properties
Data wydania: 2022
Źródło: "Materials", 2022, iss. 3, art. no. 1058, s. 1-15
Abstrakt: The Pr3+-doped solid solutions from (Ba,Ca)(Ti,Zr)O3 (BCTZO) system were successfully synthesized using an efficient and low-energy consuming route—the Pechini method combined with the sintering at relatively low temperature (1450 °C). The obtained materials were characterized by means of X-ray diffraction (XRD) and scanning electron microscopy (SEM). The dielectric properties were systematically studied. The Pr3+-doped BCTZO diphasic material generates intense and broad red photoluminescence (PL) emission at room temperature. The optical properties were significantly improved with the Ti4+ substitution by Zr4+ ions. As a result, the Pr3+-doped (Ba,Ca)(Ti,Zr)O3 ceramics is a promising candidate for environmentally friendly, multifunctional material by combining good dielectric and photoluminescent properties with prognosis for the manifestation of strong photoluminescent and mechanoluminescent effects.
URI: http://hdl.handle.net/20.500.12128/22717
DOI: 10.3390/ma15031058
ISSN: 1996-1944
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