DC pole | Wartość | Język |
dc.contributor.author | Wojnarowska, Żaneta | - |
dc.contributor.author | Cheng, Shinian | - |
dc.contributor.author | Yao, Beibei | - |
dc.contributor.author | Swadźba-Kwaśny, Małgorzata | - |
dc.contributor.author | McLaughlin, Shannon | - |
dc.contributor.author | McGrogan, Anne | - |
dc.contributor.author | Delavoux, Yoan | - |
dc.contributor.author | Paluch, Marian | - |
dc.date.accessioned | 2022-03-24T12:32:22Z | - |
dc.date.available | 2022-03-24T12:32:22Z | - |
dc.date.issued | 2022 | - |
dc.identifier.citation | "Nature Communication" (2022), vol. 13, art. no. 1342 | pl_PL |
dc.identifier.issn | 2041-1723 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.12128/22926 | - |
dc.description.abstract | Liquid−liquid transition (LLT) between two disordered phases of single-component material
remains one of the most intriguing physical phenomena. Here, we report a first-order LLT in a
series of ionic liquids containing trihexyl(tetradecyl)phosphonium cation [P666,14]+ and
anions of different sizes and shapes, providing an insight into the structure-property relationships
governing LLT. In addition to calorimetric proof of LLT, we report that ion dynamics
exhibit anomalous behavior during the LLT, i.e., the conductivity relaxation times (τσ) are
dramatically elongated, and their distribution becomes broader. This peculiar behavior is
induced by isobaric cooling and isothermal compression, with the τσ(TLL,PLL) constant for a
given system. The latter observation proves that LLT, in analogy to liquid-glass transition, has
an isochronal character. Finally, the magnitude of discontinuity in a specific volume at LLT
was estimated using the Clausius-Clapeyron equation. | pl_PL |
dc.language.iso | en | pl_PL |
dc.rights | Uznanie autorstwa 3.0 Polska | * |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/pl/ | * |
dc.subject | Liquid−liquid transition | pl_PL |
dc.subject | LLT | pl_PL |
dc.subject | ionic materials | pl_PL |
dc.title | Pressure-induced liquid-liquid transition in a family of ionic materials | pl_PL |
dc.type | info:eu-repo/semantics/article | pl_PL |
dc.identifier.doi | 10.1038/s41467-022-29021-0 | - |
Pojawia się w kolekcji: | Artykuły (WNŚiT)
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