DC pole | Wartość | Język |
dc.contributor.author | Busuev, Yuriy G. | - |
dc.contributor.author | Grosu, Yaroslav | - |
dc.contributor.author | Chorążewski, Mirosław | - |
dc.contributor.author | Meloni, Simone | - |
dc.date.accessioned | 2022-03-28T12:31:01Z | - |
dc.date.available | 2022-03-28T12:31:01Z | - |
dc.date.issued | 2022 | - |
dc.identifier.citation | "ACS Nano Letters" (2022), vol. 22, s. 2164-2169 | pl_PL |
dc.identifier.issn | 1530-6992 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.12128/22980 | - |
dc.description.abstract | Intrusion (wetting)/extrusion (drying) of liquids in/from
lyophobic nanoporous systems is key in many fields, including chromatography,
nanofluidics, biology, and energy materials. Here we demonstrate that secondary
topological features decorating main channels of porous systems dramatically
affect the intrusion/extrusion cycle. These secondary features, allowing an
unexpected bridging with liquid in the surrounding domains, stabilize the water
stream intruding a micropore. This reduces the intrusion/extrusion barrier and the
corresponding pressures without altering other properties of the system. Tuning
the intrusion/extrusion pressures via subnanometric topological features
represents a yet unexplored strategy for designing hydrophobic micropores.
Though energy is not the only field of application, here we show that the proposed
tuning approach may bring 20−75 MPa of intrusion/extrusion pressure increase,
expanding the applicability of hydrophobic microporous materials. | pl_PL |
dc.language.iso | en | pl_PL |
dc.rights | Uznanie autorstwa 3.0 Polska | * |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/pl/ | * |
dc.subject | nanoporous materials | pl_PL |
dc.subject | hydrophobic nanoparticles | pl_PL |
dc.subject | solid−liquid interface | pl_PL |
dc.subject | intrusion/extrusion | pl_PL |
dc.title | Subnanometer Topological Tuning of the Liquid Intrusion/Extrusion Characteristics of Hydrophobic Micropores | pl_PL |
dc.type | info:eu-repo/semantics/article | pl_PL |
dc.identifier.doi | 10.1021/acs.nanolett.1c02140 | - |
Pojawia się w kolekcji: | Artykuły (WNŚiT)
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