DC pole | Wartość | Język |
dc.contributor.author | Małecki, Jan Grzegorz | - |
dc.contributor.author | Machura, Barbara | - |
dc.contributor.author | Świtlicka, Anna | - |
dc.date.accessioned | 2019-06-13T10:24:56Z | - |
dc.date.available | 2019-06-13T10:24:56Z | - |
dc.date.issued | 2011 | - |
dc.identifier.citation | Structural Chemistry, Vol. 22 (2011), s. 77-87 | pl_PL |
dc.identifier.issn | 1040-0400 | - |
dc.identifier.issn | 1572-9001 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.12128/9472 | - |
dc.description.abstract | New complexes with formula [M(SCN)2(L)2]
where M = Mn(II), Cu(II) were synthesized in simple
reactions of metal chlorides with ammonia thiocyanate and
5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine (pytz) ligand in
methanol solutions. In the reaction of NiCl2 6H2O and pytz
ligand the [NiCl2(pytz)2] 2CH3OH complex was obtained.
The complexes were studied by IR, UV–vis, EPR spectroscopy
and X-ray crystallography. Electronic structures
of the complexes were calculated using DFT method, and
apart from the descriptions of frontier molecular orbitals
and the relocation of the electron density of the compounds,
the bonding properties in the complexes were
determined. | pl_PL |
dc.language.iso | en | pl_PL |
dc.rights | Uznanie autorstwa-Użycie niekomercyjne 3.0 Polska | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc/3.0/pl/ | * |
dc.subject | Manganese(II) | pl_PL |
dc.subject | Copper(II) | pl_PL |
dc.subject | Nickel(II) complexes | pl_PL |
dc.subject | 5,6-Diphenyl-3-(2-pyridyl)-1,2,4-triazine | pl_PL |
dc.subject | X-ray structure | pl_PL |
dc.subject | UV–vis | pl_PL |
dc.subject | DFT | pl_PL |
dc.subject | EPR | pl_PL |
dc.title | X-ray studies, spectroscopic characterisation and DFT calculations for Mn(II), Ni(II) and Cu(II) complexes with 5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine | pl_PL |
dc.type | info:eu-repo/semantics/article | pl_PL |
dc.identifier.doi | 10.1007/s11224-010-9686-7 | - |
Pojawia się w kolekcji: | Artykuły (WNŚiT)
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