DC pole | Wartość | Język |
dc.contributor.author | Rams-Baron, Marzena | - |
dc.contributor.author | Yao, Beibei | - |
dc.contributor.author | Cheng, Shinian | - |
dc.contributor.author | Dulski, Mateusz | - |
dc.contributor.author | Paluch, Marian | - |
dc.date.accessioned | 2021-11-17T13:37:41Z | - |
dc.date.available | 2021-11-17T13:37:41Z | - |
dc.date.issued | 2021 | - |
dc.identifier.citation | "The Journal of Physical Chemistry Letters" (2021), iss. 0, s. 11303-11307 | pl_PL |
dc.identifier.issn | 1948-7185 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.12128/21888 | - |
dc.description.abstract | We present the results of dielectric measurements for three sizable glass-formers
with identical nonpolar cores linked to various dipole-labeled rotors that shed new light on the
picture of reorientation of anisotropic systems with significant moment of inertia revealed by
broadband dielectric spectroscopy. The dynamics of sizable glass-formers formed by partially
rigid molecular cores linked to small polar rotors in many respects differs from that of typical
glass-formers. For instance, the extraordinarily large prefactors (τ0 > 10−12 s) in the Vogel−
Fulcher−Tammann equation were found. The rich and highly diverse relaxation pattern was
governed by the location of a dipole, its ability to rotate freely, and the degree of coupling to the
motion of the entire sizable system. | pl_PL |
dc.language.iso | en | pl_PL |
dc.rights | Uznanie autorstwa 3.0 Polska | * |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/pl/ | * |
dc.subject | sizable glass-formers | pl_PL |
dc.subject | dielectric measurements | pl_PL |
dc.subject | dielectric spectroscopy | pl_PL |
dc.subject | polar rotors revealed | pl_PL |
dc.title | Complex reorientation dynamics of sizable glass-formers with polar rotors revealed by dielectric spectroscopy | pl_PL |
dc.type | info:eu-repo/semantics/article | pl_PL |
dc.identifier.doi | 10.1021/acs.jpclett.1c03088 | - |
Pojawia się w kolekcji: | Artykuły (WNŚiT)
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