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Title: Styrene epoxidation over heterogeneous manganese(III) complexes
Authors: Kuźniarska-Biernacka, Iwona
Lisińska-Czekaj, Agata
Czekaj, Dionizy
José Alves, Maria
Mauricio Fonseca, Antonio
Correia Neves, Isabel
Keywords: Catalyst selectivity; Catalysts; Manganese; Spectroscopic analysis; Styrene; Zeolites
Issue Date: 2016
Citation: Archives of Metallurgy and Materials, 2016, iss. 3, s. 1477-1482
Abstract: The manganes(III) complex functionalised with 2,3-dihydropyridazine has been encapsulated in the supercages of the NaY zeolite using two different procedures, flexible ligand and in situ complex. The parent zeolite and the encapsulated manganese(III) complexes were screened as catalysts for styrene oxidation by using t-BOOH as the oxygen source in acetonitrile. Under the optimized conditions, the catalysts exhibited moderate activity with high selectivity to benzaldehyde (spectroscopic grade) used for FTIR analysis was purchased from Merck.
DOI: 10.1515/amm-2016-0242
ISSN: 1733-3490
Appears in Collections:Artykuły (WNŚiT)

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