http://hdl.handle.net/20.500.12128/3273
Title: | Styrene epoxidation over heterogeneous manganese(III) complexes |
Authors: | Kuźniarska-Biernacka, Iwona Lisińska-Czekaj, Agata Czekaj, Dionizy José Alves, Maria Mauricio Fonseca, Antonio Correia Neves, Isabel |
Keywords: | Catalyst selectivity; Catalysts; Manganese; Spectroscopic analysis; Styrene; Zeolites |
Issue Date: | 2016 |
Citation: | Archives of Metallurgy and Materials, 2016, iss. 3, s. 1477-1482 |
Abstract: | The manganes(III) complex functionalised with 2,3-dihydropyridazine has been encapsulated in the supercages of the NaY zeolite using two different procedures, flexible ligand and in situ complex. The parent zeolite and the encapsulated manganese(III) complexes were screened as catalysts for styrene oxidation by using t-BOOH as the oxygen source in acetonitrile. Under the optimized conditions, the catalysts exhibited moderate activity with high selectivity to benzaldehyde (spectroscopic grade) used for FTIR analysis was purchased from Merck. |
URI: | http://hdl.handle.net/20.500.12128/3273 |
DOI: | 10.1515/amm-2016-0242 |
ISSN: | 1733-3490 |
Appears in Collections: | Artykuły (WNŚiT) |
File | Description | Size | Format | |
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Kuzniarska-Biernacka_Styrene_epoxidation_over_heterogeneous_manganese_complexes.pdf | 917,28 kB | Adobe PDF | View/Open |
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