http://hdl.handle.net/20.500.12128/8022
Title: | Crystal Structure of (NbSe4)3I and (NbSe4)10/3I CDW Compounds at 14 K |
Authors: | Zubko, Maciej Kusz, Joachim Prodan, A. Bennett, J.C. Świec, Paweł |
Keywords: | niobium compounds; crystal structure |
Issue Date: | 2016 |
Citation: | Acta Physica Polonica. A, Vol. 130, nr 4 (2016), s. 869-872 |
Abstract: | Both (NbSe4)3I and (NbSe4)10=3I compounds are interesting system possessing quasi one-dimensional linear chain character and exhibiting nonlinear transport properties with a second order phase transition. The compounds are built of NbSe4 antiprisms, stacked along the tetragonal c axis into chains in a screw-like arrangement. Performed X-ray low temperature single crystal diffraction measurements allowed to solve, refine and analyze crystal structures of both compounds at 14 K. While (NbSe4)10=3I compound undergoes structural phase transition to monoclinic phase, (NbSe4)3I remains in tetragonal symmetry. Iodine atoms are responsible for the differences in (NbSe4)10=3I and (NbSe4)3I structures causing different spacing in the infinite NbSe4 chains. |
URI: | http://hdl.handle.net/20.500.12128/8022 |
DOI: | 10.12693/APhysPolA.130.869 |
ISSN: | 0587-4246 |
Appears in Collections: | Artykuły (WNŚiT) |
File | Description | Size | Format | |
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Zubko_Crystal_Structure_of_NbSe4_3I.pdf | 1,34 MB | Adobe PDF | View/Open |
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