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http://hdl.handle.net/20.500.12128/9322| Title: | A copper(I) phosphine complex with 5,7-dinitro-2-methylquinolin-8-ol as co-ligand |
| Authors: | Małecki, Jan Grzegorz Maroń, Anna Palion, Joanna Nycz, Jacek E. Szala, Marcin |
| Keywords: | ligands; copper |
| Issue Date: | 2014 |
| Citation: | Transition Metal Chemistry, 2014, iss. 7, s. 755-762 |
| Abstract: | 5,7-Dinitro-2-methylquinolin-8-ol has been synthesized, and its copper(I) complex has been prepared. Both the free 2-MequinNO2 ligand and its complex were characterized by IR, NMR, and UV–Vis spectra. The structure of the [Cu(2-MequinNO2)(PPh3)2] complex has been determined by single-crystal X-ray analysis. The free 2-MequinNO2 ligand reveals luminescence in contrast to the complex. For 2-MequinNO2, the quantum yield, lifetime of the excited state, and the rate constants of both radiative and non-radiative decay have been determined. The lack of luminescence for the complex has been explained with the use of a quantum chemical study. |
| URI: | http://hdl.handle.net/20.500.12128/9322 |
| DOI: | 10.1007/s11243-014-9857-2 |
| ISSN: | 0340-4285 |
| Appears in Collections: | Artykuły (WNŚiT) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Malecki_A_copper(I)_phosphine_complex.pdf | 988,7 kB | Adobe PDF | View/Open |
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