http://hdl.handle.net/20.500.12128/9330
Title: | A ruthenium(II) hydride carbonyl complex with 4-phenylpyrimidine as co-ligand |
Authors: | Małecki, Jan Grzegorz Maron, A. |
Keywords: | ruthenium; X ray crystallography |
Issue Date: | 2012 |
Citation: | Transition Metal Chemistry, 2012, iss. 8, s. 727-734 |
Abstract: | The reaction of [RuHCl(CO)(PPh3)3] with 4-phenylpyrimidine gave a new ruthenium(II) complex, namely [RuHCl(CO)(PPh3)2(pyrim-4-Ph)]. The complex has been studied by IR and UV–vis spectroscopy and by X-ray crystallography. The molecular orbitals of the complex have been calculated by density functional theory. The spin-allowed singlet–singlet electronic transitions of the complex have been calculated by time-dependent DFT, and the UV–vis spectrum of the compound has been discussed on this basis. The emission properties of the complex were also studied. |
URI: | http://hdl.handle.net/20.500.12128/9330 |
DOI: | 10.1007/s11243-012-9644-x |
ISSN: | 0340-4285 |
Appears in Collections: | Artykuły (WNŚiT) |
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Malecki_A_ruthenium(II)_hydride_carbonyl.pdf | 572,09 kB | Adobe PDF | View/Open |
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