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Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12128/9430
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dc.contributor.authorKrompiec, Stanisław-
dc.contributor.authorPenkala, Mateusz-
dc.contributor.authorKowalska, Ewelina-
dc.contributor.authorPenczek, Robert-
dc.contributor.authorBujak, Piotr-
dc.contributor.authorDanikiewicz, Witold-
dc.contributor.authorSpólnik, Grzegorz-
dc.contributor.authorKita, Andrzej-
dc.contributor.authorGrudzka, Iwona-
dc.date.accessioned2019-06-11T09:06:40Z-
dc.date.available2019-06-11T09:06:40Z-
dc.date.issued2011-
dc.identifier.citationMonatshefte für Chemie, Vol. 142 (2011), s. 1241-1247pl_PL
dc.identifier.issn0026-9247-
dc.identifier.issn1434-4475-
dc.identifier.urihttp://hdl.handle.net/20.500.12128/9430-
dc.description.abstractRu-catalyzed synthesis of mixed alkyl–alkyl acetals via addition of primary alcohols to allyl ethers has been extended to include long-chain and/or functionalized substrates. The catalytic systems for these reactions were generated from RuCl2(PPh3)3 and [RuCl2(1,5-COD)]x and phosphines [PPh3 or P(p-chlorophenyl)3] or SbPh3 . Of particular importance is the almost quantitative elimination of transacetalization. The addition proceeds through allyl complexes, not via isomerization of allyl ethers––subsequent addition of ROH to vinyl ethers.pl_PL
dc.language.isoenpl_PL
dc.rightsUznanie autorstwa-Użycie niekomercyjne 3.0 Polska*
dc.rights.urihttp://creativecommons.org/licenses/by-nc/3.0/pl/*
dc.subjectChemoselectivitypl_PL
dc.subjectHomogeneus catalysispl_PL
dc.subjectMetal complexespl_PL
dc.subjectMixed acetalspl_PL
dc.titleSynthesis of unsymmetrical alkyl acetals via addition of primary alcohols to allyl ethers mediated by ruthenium complexespl_PL
dc.typeinfo:eu-repo/semantics/articlepl_PL
dc.identifier.doi10.1007/s00706-011-0638-8-
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