http://hdl.handle.net/20.500.12128/9430
Title: | Synthesis of unsymmetrical alkyl acetals via addition of primary alcohols to allyl ethers mediated by ruthenium complexes |
Authors: | Krompiec, Stanisław Penkala, Mateusz Kowalska, Ewelina Penczek, Robert Bujak, Piotr Danikiewicz, Witold Spólnik, Grzegorz Kita, Andrzej Grudzka, Iwona |
Keywords: | Chemoselectivity; Homogeneus catalysis; Metal complexes; Mixed acetals |
Issue Date: | 2011 |
Citation: | Monatshefte für Chemie, Vol. 142 (2011), s. 1241-1247 |
Abstract: | Ru-catalyzed synthesis of mixed alkyl–alkyl acetals via addition of primary alcohols to allyl ethers has been extended to include long-chain and/or functionalized substrates. The catalytic systems for these reactions were generated from RuCl2(PPh3)3 and [RuCl2(1,5-COD)]x and phosphines [PPh3 or P(p-chlorophenyl)3] or SbPh3 . Of particular importance is the almost quantitative elimination of transacetalization. The addition proceeds through allyl complexes, not via isomerization of allyl ethers––subsequent addition of ROH to vinyl ethers. |
URI: | http://hdl.handle.net/20.500.12128/9430 |
DOI: | 10.1007/s00706-011-0638-8 |
ISSN: | 0026-9247 1434-4475 |
Appears in Collections: | Artykuły (WNŚiT) |
File | Description | Size | Format | |
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Krompiec_Synthesis_of_unsymmetrical_alkyl_acetals_via_addition.pdf | 809,99 kB | Adobe PDF | View/Open |
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